HARD
SURFACE MARKER SAFETY DATA SHEET
FOR
GRASSLINE READY
SPRAY
IDENTIFICATION OF THE
SUBSTANCE / PREPARATION AND OF THE COMPANY / UNDERTAKING
Product
name: GRASSLINE READY SPRAY
Use
/ description of product: Extremely
flammable. Liquid.
COMPOSITION
/ INFORMATION ON INGREDIENTS
Ingredient
1: 1-METHOXY-2-PROPANOL <3%
CAS:
107-98-2
EINECS:
203-539-1
[-]
R10;
Ingredient
2: AROMATIC HYDROCARBONS BPT 160/180 <3%
[-]
R10; [Xn] R65;
Ingredient
3: ACETONE 10-20%
CAS:
67-64-1
EINECS:
200-662-2
[F]
R11; [Xi] R36; [Xi] R66; [-] R67;
Ingredient
4: DIMETHYL ETHER 10-20%
CAS:
115-10-6
EINECS:
204-065-8
[F+]
R12;
Ingredient
5: ISOBUTANE <3%
CAS:
75-28-5
EINECS:
200-857-2
[F+]
R12;
Ingredient
6: BUTANE 5-10%
CAS:
106-97-8
EINECS:
203-448-7
[F+]
R12;
Ingredient
7: PROPANE 5-10%
CAS:
74-98-6
EINECS:
200-827-9
Ingredient
8: N-BUTYL ACETATE 10-20%
CAS:
123-86-4
EINECS:
204-658-1
[-]
R10; [Xi] R66; [-] R67;
HAZARDS IDENTIFICATION
Main
hazards: Extremely flammable. Repeated exposure may
cause skin dryness or cracking. Vapours may cause drowsiness
and dizziness.
Other
hazards: In use, may form flammable / explosive vapour-air
mixture.
FIRST AID MEASURES (SYMPTOMS)
Skin
contact: There may be
irritation and redness at the site of contact.
Eye
contact: There may be irritation and redness. Corneal
burns may occur.
Ingestion:
Nausea and stomach pain may occur. There may be vomiting and
diarrhoea. There may be loss of consciousness. Convulsions
may occur.
Inhalation:
Exposure may cause coughing or wheezing. There may be congestion
of the lungs causing severe shortness of breath. There may
be loss of consciousness. Convulsions may occur.
FIRST AID MEASURES (ACTION)
Skin
contact: Remove all contaminated clothes and footwear
immediately unless stuck to skin. Drench the affected
skin with running water for 10 minutes or longer if substance
is still on skin. Transfer to hospital if there are burns
or symptoms of poisoning.
Eye
contact: Bathe the eye with running water for 15 minutes.
Transfer to hospital for specialist examination.
Ingestion:
Do not induce vomiting. If conscious, give 1 pint of water
to drink immediately. If unconscious, check for breathing
and apply artificial respiration if necessary. If unconscious
and breathing is OK, place in the recovery position. Transfer
to hospital as soon as possible.
Inhalation:
Remove casualty from exposure ensuring one's own safety whilst
doing so. If unconscious, check for breathing and apply artificial
respiration if necessary. If unconscious and breathing is
OK, place in the recovery position. If conscious, ensure the
casualty sits or lies down. If breathing becomes bubbly, have
the casualty sit and provide oxygen if available. Transfer
to hospital as soon as possible.
FIRE-FIGHTING MEASURES
Extinguishing
media: Carbon dioxide. Alcohol resistant foam.
Exposure
hazards: Extremely flammable. Vapour may travel considerable
distance to source of ignition and flash back. Forms explosive
air-vapour mixture.
Protection
of fire-fighters: Wear self-contained breathing apparatus.
Wear protective clothing to prevent contact with skin and
eyes.
ACCIDENTAL RELEASE MEASURES
Personal
precautions: Eliminate all sources of ignition. Mark
out the contaminated area with signs and prevent access to
unauthorised personnel.
Environmental
precautions: Do not discharge into drains or rivers.
Contain the spillage using bunding.
Clean-up
procedures: Mix with sand or vermiculite. If inside,
transfer outside of building in suitable containers.
For small spills, absorb on to paper and allow to evaporate
in a fume cupboard. Wash the spillage site with large amounts
of water.
HANDLING AND STORAGE
Handling
requirements: Ensure there is sufficient ventilation
of the area. Avoid direct contact with the substance. Smoking
is forbidden.
Storage
conditions: Store in cool, well ventilated area. Keep
away from sources of ignition. Keep container tightly closed.
Ensure lighting and electrical equipment are not a source
of ignition.
EXPOSURE CONTROLS / PERSONAL
PROTECTION
Engineering
measures: Ensure there is sufficient ventilation of
the area. Ensure lighting and electrical equipment are not
a source of ignition.
Respiratory
protection: Self-contained breathing apparatus must
be available in case of emergency.
Hand
protection: Protective gloves.
Eye
protection: Safety goggles.
Skin
protection: Protective clothing with elasticated cuffs
and closed neck. Boots made of PVC.
PHYSICAL AND CHEMICAL PROPERTIES
State:
Aerosol
Colour:
White
Odour:
Characteristic odour
Oxidising:
Non-oxidising (by EC criteria)
Solubility
in water: Insoluble
Flammability
limits %: lower: 0.8 upper: 18.6
STABILITY AND REACTIVITY
Stability:
Stable under normal conditions.
Conditions
to avoid: Sources of ignition. Flames. Heat.
Materials
to avoid: Strong oxidising agents. Mineral Acids. Strong
alkalis.
Haz.
decomp. products: In combustion emits toxic fumes of
carbon dioxide and carbon monoxide.
TOXICOLOGICAL INFORMATION
Effects of exposure May cause
irritation to the respiratory system. Solvent vapours are
hazardous and may cause nausea, sickness and headaches. Prolonged
inhalation of high concentrations may damage respiratory system.
May cause discomfort if swallowed. May cause stomach pain
or vomiting. Gastrointestinal symptoms, including upset stomach.
Prolonged or repeated exposure may cause severe iritation.
Acts as a defatting agent on skin. May cause cracking of skin,
and eczema. Irritating to eyes.
Routes of exposure Inhalation. Skin and/or
eye contact.
Ingredient 1: 1-METHOXY-2-PROPANOL
IVN
RAT LD50 4200mg/kg
ORL
MUS LD50 11700mg/kg
ORL RAT LDLO 3739mg/kg
Ingredient 3: ACETONE
IVN
RAT LD50 5500mg/kg
ORL
MUS LD50 3gm/kg
ORL RAT LD50 5800mg/kg
Ingredient 8: N-BUTYL
ACETATE
ORL
MUS LD50 6gm/kg
ORL RAT LD50 10768mg/kg
ECOLOGICAL INFORMATION
Other adverse effects: Dangerous
for the environment if discharged into watercourses.
DISPOSAL CONSIDERATIONS
Waste
disposal: Dispose of in accordance
with local authority regulations.
Disposal
of packaging Empty containers must not be burned because of
explosion hazard.NB: The user's attention is drawn to the
possible existence of regional or national regulations regarding
disposal.
TRANSPORT INFORMATION
ADR
/ RID
UN
no: 1950
ADR
Class: 2
Labelling:
2.1
Shipping
name: AEROSOLS
IMDG
/ IMO
UN
no: 1950
Class:
2
EmS:
F-D,S-U
Marine
pollutant: .
Labelling:
2.1
IATA
/ ICAO
UN
no: 1950
Class:
2
Labelling:
2.1
REGULATORY INFORMATION
Hazard
symbols: Extremely flammable.
Risk
phrases:
R12:
Extremely flammable.
R66:
Repeated exposure may cause skin dryness or cracking.
R67:
Vapours may cause drowsiness and dizziness.
Safety
phrases:
S2:
Keep out of the reach of children.
S16:
Keep away from sources of ignition - No smoking.
S23:
Do not breathe vapour.
S37:
Wear suitable gloves.
S51:
Use only in well-ventilated areas.
Pressurized container: protect
from sunlight and do not expose to temperatures exceeding
50°C. Do not pierce or burn, even after use.
Note: The
regulatory information given above only indicates the principal
regulations specifically applicable to the product described
in the safety data sheet. The user's attention is drawn to
the possible existence of additional provisions which complete
these regulations. Refer to all applicable national, international
and local regulations or provisions.
ADDITIONAL INFORMATION
Risk
phrases used in s.2:
R10:
Flammable.
R65:
Harmful: may cause lung damage if swallowed.
R11:
Highly flammable.
R36:
Irritating to eyes.
R66:
Repeated exposure may cause skin dryness or cracking.
R67:
Vapours may cause drowsiness and dizziness.
R12:
Extremely flammable.
Legal disclaimer: The above
information is believed to be correct but does not purport
to be all inclusive and shall be used only as a guide. This
company shall not be held liable for any damage resulting
from handling or from contact with the above product.
Issued
by VFM Products Limited.
Registered
Office:
Anchor
House
Dewsbury
Mills
Thornhill
Road
Dewsbury
West
Yorkshire
WF12
9QE
Tel: 01924 462956
Fax: 01924 439785
email
info@vfmltd.com
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